重金属的土水分配行为研究——根际土壤溶液采样器的应用
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国家自然科学基金项目(40772155)、咸宁学院重点项目(BK0704)和生物地质与环境地质教育部重点实验室开放基金项目(BGEG0809)资助。


Study on soil-water distribution coefficients of heavy metals by Rhizon-SMS
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    摘要:

    采用根际土壤溶液采样器(Rhizon-SMS)原位采集河南平原耕地土壤溶液。用土壤溶液中重金属浓度对数作为因变量、土壤溶液理化性质作为自变量,进行多元线性逐步回归,结果表明:只有有机碳进入Cu的相关方程,pH进入Cd的相关方程。土壤溶液pH和土壤中的Zn都作为自变量进入Zn的相关方程。土壤溶液中的Cu与pH没有线性关系,而Cd和Zn与土壤溶液pH有显著的线性关系(p<0.01)。计算了土壤中Cu、Cd、Zn在土壤与土壤溶液中的分配系数Kd。本研究中,3种重金属的Kd大小顺序为:Cu>Zn>Cd。根据Freeze 和Cherry模型,联合log(Kd-Cd)、log(Kd-Zn)与pH的线性关系,估计了Cd和Zn在土壤中的迁移速度。

    Abstract:

    In situ soil solutions in cultivated land in Henan Plain were sampled by rhizon soil moister sampler (Rhizon-SMS). The heavy metal concentration in soil solution was predicted by semi-experience model which were obtained by statistical method. A function including organic carbon content of soils was obtained for Cu in soil solution, a function including soil pH for Cd in soil solution, and a function including soil pH and total Zn content in soil for Zn in soil solution. Cu concentration in soil solution showed no linear correlation with soil pH, but Cd and Zn concentrations in soil solution showed positive correlation with soil pH. The distribution coefficient (Kd) for Cu, Cd, and Zn in soil-solution phase were calculated. The Kd for Cu, Cd, and Zn was in order as Cu > Zn> Cd. Those showed that the mobility of Cu, Cd, and Zn in soil was in order as Cd > Zn > Cu. Log (Kd-Cd) and log (Kd-Zn) showed simple linear correlations with soil pH and the obtained functions were significant (p<0.01). Based on Freeze and Cherry model, combined with log (Kd-Cd) and log (Kd-Zn) linear correlations with soil pH, Cd and Zn migration velocities in soil were estimated. The lower migration velocity of Cd in soil suggested most Cd accumulated in 0 ~ 15 cm topsoil, but Zn migrated further downward in soil profile.

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郝汉舟,靳孟贵,李瑞敏,王支农,刘成武,陈 志,钟学斌.重金属的土水分配行为研究——根际土壤溶液采样器的应用[J].土壤,2009,41(4):577-582. HAO Han-zhou, JIN Meng-gui, LI Rui-min, WANG Zhi-nong, LIU Cheng-wu, CHEN Zhi, ZHONG Xue-bin. Study on soil-water distribution coefficients of heavy metals by Rhizon-SMS[J]. Soils,2009,41(4):577-582

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