The spatial distribution characteristic of Cu, Pb, Zn, Cd, Ni, Cr, Hg, As and polychlorinated biphenyls (PCBs) were studied and the possibility of forecasting the state of contamination with the distribution of enterprise was discussed in a typical enterprise-intensive area. The results indicated that compound pollution with heavy metals, PCBs in the dismantling electronic wastes and small scale smelting exist in the studied area. The enterprises producing metal products, power engines, wires and cables increased the concentrations of Cu and Pb in within a 1 km2 peripheral soil. The enterprises making power engines, producing wires and cables could lead to Pb accumulation in soil. There were significant correlations between the concentrations of Cd, Ni, Cr and the spatial distribution of the enterprises producing metals. And the enterprises producing mobile and metal accessories could cause the accumulations of As and PCBs respectively.