滇池外海沉积物中滴滴涕类农药的残留特征
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云南省自然科学基金重点项目(2009CC0006)资助


Residue Characteristics of DDTs in Surface Sediments of Waihai, Dianchi Lake
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    摘要:

    滴滴涕类农药(DDTs)既是环境内分泌干扰物,也是持久性有机污染物,为了解滇池沉积物中DDTs的残留水平,本文采集滇池外海的18个表层沉积物样品,分析其DDTs农药的残留量,结果表明:①滇池沉积物中∑DDTs农药的含量为0.2 ~ 4.9 ng/g(干重),p,p¢-DDE和p,p¢-DDD是目前滇池外海表层沉积物中DDTs农药最主要的赋存组分,含量检测平均值为1.14 ng/g(干重)和0.78 ng/g(干重);②沉积物中的DDTs主要来源于历史残留,未发现新的污染源输入;③多数点位的WDDD/WDDE<1,表明DDTs的降解环境以好氧条件为主;④滇池外海沉积物中DDTs的残留水平低于已有报道的国内其他水体,空间分布呈现北部湖区高于中部和南部湖区的特征。

    Abstract:

    DDT pesticides (DDTs) carry typical characteristics of both environment endocrine disruptors (EEDs) and persistent organic pollutants (POPs). In order to investigate the current pollution of DDTs in Dianchi Lake, 18 surface sediments samples of Waihai, Dianchi Lake were collected and analyzed by GC-ECD. The results showed that: 1) the concentration range of ∑DDTs was 0.2 – 4.9 ng/g (dry weight), p,p’-DDE and p,p’-DDD were the main components founded in the surface sediments, the average valve were 1.14 ng/g (dry weight) and 0.78 ng/g (dry weight); 2) the DDTs in the sediments might be derived from the DDT-treated soils in aged agriculture, and no new pollution sources was found; 3)The ratio of WDDD to WDDE were lower than 1 in most sites, which indicated that aerobic conditions was the primary degradation; 4) Compared with other domestic water body reported, the pollution of ∑DDTs in the surface sediments of Waihai, Dianchi Lake was relatively lower and the residual level of ∑DDTs showed that the northern region was higher than the middle and the southern region in this study area.

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肖 洋,张乃明.滇池外海沉积物中滴滴涕类农药的残留特征[J].土壤,2014,46(4):684-688. XIAO Yang, ZHANG Nai-ming. Residue Characteristics of DDTs in Surface Sediments of Waihai, Dianchi Lake[J]. Soils,2014,46(4):684-688

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  • 在线发布日期: 2014-09-12
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