炭化温度对沙蒿生物炭形貌特征和化学性质的影响
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国家自然科学基金项目(31260502)资助


Effects of Carbonization Temperature on Artemisia ordosica Biochar Morphology and Chemical Properties
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    摘要:

    沙蒿是半灌木典型沙生植物,作为制炭物料具有其特殊性,而炭化温度决定生物炭形貌特征和化学性质。通过无氧炭化法制备了不同温度(300 ~ 900℃)的沙蒿生物炭,研究了炭化温度对沙蒿生物炭形貌特征、表面官能团种类、产率变化和有机组分含量的影响。结果表明:生物炭孔径随着炭化温度的升高而增大,700℃以后生物炭结构有一定程度的破坏;生物质炭化后C–O–C、–COOH、–CH3、–CH2、–OH和C=O逐渐消失;生物炭产率随着炭化温度的升高而降低,尤其是从 300℃升高至 400℃产率降低最为明显,这与纤维素及半纤维素的分解有直接关系;生物炭中有机组分的C元素含量增加,由 701.7 g/kg 增加到 899.3 g/kg,增加了 197.6 g/kg;而H、O和N元素含量则逐渐降低,分别降低了21.4、171.8 和 6.6 g/kg;生物炭中有机组分的原子比 H/C、O/C 和 (N + O)/C?都逐渐减小。总之,生物质升温炭化过程中,炭化温度与生物炭孔径及有机组分的C元素含量呈正相关关系而与生物炭产率、生物炭中有机组分的H、O和N元素含量呈负相关关系,低温和中温炭化时生物炭保留原有的骨架结构,而高温时对其有一定程度的破坏作用,沙蒿生物质含有丰富的官能团,升温裂解过程中多数官能团消失,无机组分 Si–O–Si?得以保留,此外,生物质升温裂解是一个芳香性逐渐增强,亲水性和极性逐渐减弱的过程。

    Abstract:

    As a typical psammophyte subshrub, Artemisia ordosica plays a particular role in making charcoal materials. However, the morphology and chemical properties of biochar mainly depend on carbonization temperature. In the present study, Artemisia ordosica biochar at a range of 300 – 900℃ under anaerobic carbonization condition was prepared, and the effects of carbonization temperature on porosity, surface functional groups, biochar yield and organic components of the Artemisia ordosica biochar were investigated. The results indicated that the biochar porosity increased with the increase of temperature, biochar structure was damaged to some extent after 700℃; C–O–C, –COOH, –CH3, –CH2, –OH and C=O gradually disappeared after carbonization; biochar yield decreased with the increase of temperature, particularly in 300 –?400 ℃; the cellulose and semicellulose greatly decomposed with the increase of temperature within 300 – 400 ℃; the carbon content in biochar increased from 701.7 g/kg to 899.3 g/kg, increased by 197.6 g/kg; however, the contents of hydrogen, oxygen and nitrogen decreased by 21.4 g/kg, 171.8 g/kg and 6.6 g/kg, respectively; H/C, O/C and ( N + O) /C gradually reduced. In summary, when the biomass was heated and carbonized, carbonization temperature was positively related to biochar porosity and carbon contents of organic components, while was negatively correlated to biochar yield, hydrogen, oxygen and nitrogen content of biochar. The original biochar structure was preserved under low-moderate temperature. However, high temperature destroyed the biochar structure to a degree. Artemisia ordosica biomass contain plenty of functional group. The most of functional groups disappeared with the increase of the pyrolytic temperature and the composition of Si–O–Si was left. In addition, the biomass heating pyrolysis is a process which aromaticity is increased and hydrophilic and polarity are gradually decreased.

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侯建伟,索全义,梁 桓,韩雪琦,刘长涛.炭化温度对沙蒿生物炭形貌特征和化学性质的影响[J].土壤,2014,46(5):814-818. HOU Jian-wei, SUO Quan-yi, LIANG Huan, HAN Xue-qi, LIU Chang-tao. Effects of Carbonization Temperature on Artemisia ordosica Biochar Morphology and Chemical Properties[J]. Soils,2014,46(5):814-818

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  • 在线发布日期: 2014-11-18
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