基于通径分析的土壤性质与硒形态的关系——以黑龙江省主要类型土壤为例
作者:
作者单位:

中国农业大学,黑龙江省农业科学院 土壤肥料与环境资源研究所 黑龙江省土壤环境与植物营养重点实验室,黑龙江省农业科学院 土壤肥料与环境资源研究所 黑龙江省土壤环境与植物营养重点实验室,黑龙江省农业科学院 土壤肥料与环境资源研究所 黑龙江省土壤环境与植物营养重点实验室,黑龙江省农业科学院 土壤肥料与环境资源研究所 黑龙江省土壤环境与植物营养重点实验室,黑龙江省农业科学院 土壤肥料与环境资源研究所 黑龙江省土壤环境与植物营养重点实验室,黑龙江省农业科学院 土壤肥料与环境资源研究所 黑龙江省土壤环境与植物营养重点实验室

中图分类号:

S151.9

基金项目:

公益性行业(农业)科研专项经费(201303106)资助。


Relationship Between Soil Physico-chemical Properties and Selenium Species Based on Path Analysis——A Case Study of the Main Type Soils in Heilongjiang Province, China
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Affiliation:

Soil Fertilizer and Environment Resources Institute,Heilongjiang Academy of Agriculture Sciences,Key Laboratory of Soil Environment and Plant Nutrition of Heilongjiang Province,Soil Fertilizer and Environment Resources Institute,Heilongjiang Academy of Agriculture Sciences,Key Laboratory of Soil Environment and Plant Nutrition of Heilongjiang Province,Soil Fertilizer and Environment Resources Institute,Heilongjiang Academy of Agriculture Sciences,Key Laboratory of Soil Environment and Plant Nutrition of Heilongjiang Province,Soil Fertilizer and Environment Resources Institute,Heilongjiang Academy of Agriculture Sciences,Key Laboratory of Soil Environment and Plant Nutrition of Heilongjiang Province,Soil Fertilizer and Environment Resources Institute,Heilongjiang Academy of Agriculture Sciences,Key Laboratory of Soil Environment and Plant Nutrition of Heilongjiang Province,Soil Fertilizer and Environment Resources Institute,Heilongjiang Academy of Agriculture Sciences,Key Laboratory of Soil Environment and Plant Nutrition of Heilongjiang Province,Soil Fertilizer and Environment Resources Institute,Heilongjiang Academy of Agriculture Sciences,Key Laboratory of Soil Environment and Plant Nutrition of Heilongjiang Province

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    摘要:

    黑龙江省是缺硒(Se)比较严重的省份之一,位于全国低Se带的始端。本文选择黑龙江省不同类型土壤,采用连续浸提法测定了土壤中Se的形态,并运用通径分析法研究了土壤理化性质对土壤Se形态、全Se的影响。结果表明:总Se含量在不同类型土壤中差异较大,整体上处于中等偏低水平;各结合态Se中以有机态和残渣态为主,分别占8.16% ~ 50.5% 和26.32% ~ 70.90%,酸溶态占0.80% ~ 33.97%,而水溶态与交换态仅占0.70% ~ 7.18% 和0.75% ~ 9.37%。通径分析显示,土壤理化性质通过直接和间接作用共同影响着土壤各赋存形态Se的含量和分解转化方向,但其各自的作用机理和影响强度不同。在土壤各性质中,土壤有效铁、锰和黏粒以及它们间的共同作用决定了土壤Se形态分布,其中,土壤有效铁对于除残渣态Se之外的4种形态Se的生成转化起到了主导作用,而土壤有机碳、pH等其他性质主要通过正或负的间接作用影响Se形态。土壤总Se方面,土壤有效铁、锰及黏粒含量对总Se有较强的富集作用,但土壤有机碳和pH等因素间的相互作用也不可忽略。

    Abstract:

    Samples of different kinds of soils were collected from Heilongjiang Province for analysis of Selenium (Se) species using a sequential extraction method. Se in soils may be partitioned into: 1) water soluble Se (SOL-Se), 2) exchangeable Se and Se bound to carbonate (EX-Se), 3) Acid soluble Se (FMO-Se), 4) Se bound to organic matters (OM-Se), 5) residual Se (RES-Se). Relationships between soil physico-chemical properties and Se species were investigated with path analysis. Results showed that total Se content in the soils from the province was low, but varied with soil types. In terms of Se species, Se in the soils existed mainly in the forms of OM-Se and RES-Se, which accounted for 8.16%–50.5% and 26.32%–70.90% of total Se, respectively. FMO-Se accounted for 0.80%–33.97%, but SOL-Se and EX-Se only accounted for 0.70%–7.18% and 0.75%–9.37% of total Se in the soils, respectively. The results of path analysis indicated that soil properties affected transformation direction and contents of Se species directly or indirectly, but their influencing mechanisms were different. Soil available iron (aFe) showed stronger positive effects on MO-Se, FMO-Se, SOL-Se and EX-Se. The contents of aFe, available Mn (aMn) and clay as well as the interaction among them determined largely the distribution of Se species in the soils. Soil organic carbon (SOC) and pH had indirect impacts on Se forms positively or negatively. The contents of aFe, aMn and clay also showed stronger direct impacts on soil total Se content. The interaction between soil SOC and pH could have certain influence on soil total Se.

    参考文献
    [1] 中国环境监测总站, 中国土壤元素背景值[S].北京: 中国环境科学出版社, 1990: 134-137, 370-373.
    [2] Geerke H. Floor, Gabriela Román-Ross. Selenium in volcanic environments: A review[J]. Applied Geochemistry, 2012, 27(3): 517-531.
    [3] GQ Yang, ZHZH Wang, RH Zhou, et al. Endemic selenium intoxication of humans in China[J]. The American Journal of Clinical Nutrition, 1983(37): 872-881.
    [4] 朱建明, 梁小兵, 凌宏文, 等. 环境中硒存在形式的研究现状[J].矿物岩石地球化学通报.2003, 22(1), 75-81
    [5] Antana A., Jadvyg L., Sarunas A. et al. Selenium concentration dependence on soil properties[J].Journal of Food, Agriculture Environment, 2008. 1(6): 163-167.
    [6] 田应兵, 陈 芬, 熊明彪, 等. 若尔盖高原湿地土壤硒的数量、形态与分布[J].水土保持学报. 2004, 18(3), 66-70.
    [7] 张艳玲, 潘根兴, 胡秋辉, 等. 江苏省几种低硒土壤中硒的形态分布及生物有效性[J].植物营养与肥料学报. 2002, 8(3), 355-359.
    [8] 盖钧镒. 试验统计方法[M].(第四版).北京: 中国农业出版社, 2013, 1-150.
    [9] 瞿建国, 徐伯兴, 龚书椿. 连续浸提技术测定土壤和沉积物中硒的形态[J]. 环境化学, 1997, 16(3): 277-283.
    [10] 中华人民共和国国家环境保护标准. HJ680-2013《土壤和沉积物 汞、砷、硒、铋、锑的测定 微波消解/原子荧光法》[S]
    [11] MASTERSIZER 2000 MANUAL [S].
    [12] MULTI N/C 2100 /2100S 中文说明书[S].
    [13] 鲁如坤. 土壤农业化学分析方法[M]. 北京:中国农业科技出版社,2000.
    [14] JA Tan, WY Zhu, WY Wang, et al. Selenium in soil and endemic diseases in China[J]. Science of the Total Environment, 2002. 284(1): 227 - 235.
    [15] 王松山, 梁东丽, 魏 威, 等. 基于路径分析的土壤性质与硒形态的关系[J].土壤学报, 2011, 48(4), 823-830.
    [16] Wang, J., Li, H., Li, Y., et al., Speciation, Distribution, and Bioavailability of Soil Selenium in the Tibetan Plateau Kashin-Beck Disease Area-A Case Study in Songpan County, Sichuan Province, China.Biological Trace Ele-ment Research, 2013. 156(1-3): 367-375.
    [17] Gerla,P.J., M.U.Sharif, S.F.Korom. Geochemical processes controlling the spatial distribution of selenium in soil and water, west central South Dakota, USA.Environmental Earth Sciences, 2011. 62(7): 1551-1560.
    [18] 王子健, 孙喜平, 孙景芳. 土壤样品中Se 的结合态分析[J].中国环境科学, 1988, 8(6): 51- 54.
    [19] 郭庆雨, 张佳谊. 黑龙江省及内蒙呼伦贝尔盟地区畜禽常用植物性饲料及土壤含硒量的调查[J]. 黑龙江八一农垦大学学报, 1982, 2: 31-51.
    [20] Songshan Wang, Dongli Liang, Dan Wang. Selenium fractionation and speciation in agriculture soils and accumulation in corn (Zea mays L.) under field conditions in Shaanxi Province, China. Science of the Total Environment, 2012, 427-428,159–164.
    [21] M.C. WANG, H.M. CHEN. Forms and distribution of selenium at different depths and among particle size fractions of three Taiwan soils[J].Chemosphere, 2003. 52(3): 585-593.
    [22] Kausch, M.F.,C.E. Pallud.Modeling the impact of soil aggregate size on selenium immobilization. Biogeoscie-nces, 2013. 10(3): p. 1323-1336.
    [23] Tolu, J., Le Hecho, I., Bueno, M., et al., Selenium speciation analysis at trace level in soils.AnalyticaChimic-aActa, 2011. 684(1-2): p. 126-133.
    [24] 徐 文, 唐文浩, 邝春兰, 等. 海南省土壤中硒含量及影响因素分析[J]. 安徽农业科学, 2010(06): 3026-3027.
    [25] LI Yonghua, WANG Wuyi, LUO Kunli. Environmental behaviors of selenium in soil of typical selenosis area, China[J]. Journal of environmental sciences. 2008, 20: 859–864.
    [26] Elrashidi, M.A., Adriano, D.C., Workman, S.M., et al., Chemical Equilibria of Selenium in Soils: A Theoretical Development. Soil Science, 1987. 144(2): 141-152.
    [27] Mitchell K, Raoul-Marie C, Thomas M J, et al. Selenium sorption and isotope fractionation: Iron(III) oxides versus iron(II) sulfides[J]. Chemical Geology, 2013, 342(0): 21-28.
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徐 强,迟凤琴,匡恩俊,张久明,宿庆瑞,韩锦泽,王 伟,魏 丹.基于通径分析的土壤性质与硒形态的关系——以黑龙江省主要类型土壤为例[J].土壤,2016,48(5):992-999. XU Qiang, CHI Fengqin, KUANG Enjun, ZHANG Jiuming, SU Qingrui, Han Jinze, WANG Wei, WEI Dan. Relationship Between Soil Physico-chemical Properties and Selenium Species Based on Path Analysis——A Case Study of the Main Type Soils in Heilongjiang Province, China[J]. Soils,2016,48(5):992-999

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  • 收稿日期:2015-10-27
  • 最后修改日期:2015-12-01
  • 录用日期:2015-12-03
  • 在线发布日期: 2016-09-27
  • 出版日期: 2016-10-25
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