矿物质调理剂中铝的稳定性及其对酸性土壤的改良作用
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华南理工大学环境与能源学院,华南理工大学环境与能源学院

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中图分类号:

S156.2;S156.6

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国家科技支撑计划项目(2015BAD05B05+2)、广东省科技计划项目(20130323c)和广州市2016年污染防治新技术新工艺示范和应用项目资助。


Stability of Aluminum in Mineral Conditioners and Amelioration on Acid Soil
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School of Environment and Energy,South China University of Technology,Guangzhou Higher Education Mega Centre,School of Environment and Energy,South China University of Technology,Guangzhou Higher Education Mega Centre

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    摘要:

    通过室内土壤培养试验和模拟酸雨浸泡试验,研究了3种含铝量不同的矿物质调理剂中铝的稳定性及其对酸性土壤的改良效果。该类调理剂是利用钾长石、白云石和石灰石等合理配伍后经高温焙烧而制得,呈弱碱性,富含有效钙、镁、钾、硅等营养元素。试验结果表明,施入0.5 ~ 2 g/kg调理剂培养60 d后,土壤pH 由4.98升高到5.04 ~ 5.42,交换性铝含量下降37.40% ~ 68.90%,吸附态羟基铝含量稍有增加,但毒害性铝和活性铝总量分别降低了5.37% ~ 9.50% 和4.33% ~ 12.08%,提高土壤中交换性钙、镁、钾和有效硅的含量。同时模拟酸雨浸泡试验中铝溶出量明显降低。该类矿物质调理剂能中和土壤酸度、缓解铝毒和增加土壤养分;调理剂中铝稳定性较高,不会对土壤铝毒产生叠加效应,可安全应用于农业生产。

    Abstract:

    Indoor incubation and bathe equilibrium experiment were conducted to investigate the stability of aluminum (Al) in three Al-containing mineral conditioners and their amelioration on the acidity of soil. The mineral conditioners consist of a mixture of calcined product include potassium feldspar, dolomite and limestone powder which rich in available Ca, Mg, K, Si and other micronutrients. Results showed that soil pH value rose from 4.98 to 5.04 – 5.42 and exchangeable Al decreased by 37.40% – 68.90% after 60 days when the dosage was 0.5 – 2 g/kg soil. Even though the adsorbent hydroxyl Al increased slightly, the total toxic Al and available Al decreased by 5.37% – 9.50% and 4.33% – 12.08%, respectively. Results also suggested that exchangeable Ca, Mg, K and available Si increased, and Al concentration in the filtrate under simulated acid rain decreased significantly, which indicated that the mineral conditioners could neutralize soil acidity, eliminate Al toxicity and improve the soil fertility, and could be used in agricultural production safely due to the high stability of Al in conditioners and additive of Al toxicity avoided.

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蒙园园,石 林.矿物质调理剂中铝的稳定性及其对酸性土壤的改良作用[J].土壤,2017,49(2):345-349. MENG Yuanyuan, SHI Lin. Stability of Aluminum in Mineral Conditioners and Amelioration on Acid Soil[J]. Soils,2017,49(2):345-349

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历史
  • 收稿日期:2016-09-08
  • 最后修改日期:2016-10-11
  • 录用日期:2016-10-17
  • 在线发布日期: 2017-03-22
  • 出版日期: 2017-04-25