不同电解质对牛粪生物质炭中腐殖酸吸附–解吸的影响
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

S157.1;S157.2;S157.3

基金项目:

国家自然科学基金项目(41461061)资助。


Effects of Different Electrolytes on Adsorption-desorption Characteristics of Humic Acid in Dairy Manure Biochar
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    本文研究了NaCl、Na2SO4、Na3PO4 3种背景电解质对牛粪生物质炭中腐殖酸吸附和解吸的影响。结果表明:在这3种背景电解质作用下,牛粪生物质炭对腐殖酸的吸附量和吸附率随着加入液腐殖酸浓度的增加而增加,但是增加速度逐渐变缓。3种背景电解质相比,NaCl中牛粪生物质炭对腐殖酸的吸附量和吸附率均为最高,吸附量范围为0.13 ~ 6.10 mg/g,吸附率范围为25.40% ~ 87.14%。随着加入液腐殖酸浓度的增加,吸附态腐殖酸的解吸量逐渐增加,解吸率逐渐减小。3种背景电解质相比,Na2SO4中牛粪生物质炭吸附的腐殖酸的解吸量最高,解吸量范围为0.15 ~ 0.78 mg/g。加入液腐殖酸浓度为140 mg/L,3种背景电解质中牛粪生物质炭吸附的腐殖酸的解吸量均达到最大值,解吸量的大小顺序为Na2SO4>Na3PO4>NaCl。Na3PO4对腐殖酸的解吸率影响最大,解吸率范围为17.24% ~ 90.55%,NaCl对腐殖酸的解吸率影响最小,解吸率范围为8.22% ~ 53.54%。用Langmuir拟合3种背景电解质中腐殖酸的等温吸附曲线和等温解吸曲线,其相关系数都达到显著水平。研究结果揭示了不同背景电解质对牛粪生物质炭吸附和解吸腐殖酸的影响,可为土壤保土保肥提供理论参考。

    Abstract:

    The effects of three kinds of background electrolytes (NaCl, Na2SO4 and Na3PO4) on the adsorption and desorption of humic acid in the dairy manure biochar were studied. Results showed that under the effect of the three kinds of background electrolytes, the dairy manure biochar adsorption capacity and adsorption rate increased with the increase of liquid humic acid concentration, however, the increasing speed gradually slowed down. Compared to the three kinds of background electrolytes, NaCl had the highest adsorption capacity and adsorption rate of humic acid in dairy manure biochar, The range of adsorption capacity was 0.13–6.10 mg/g, the range of adsorption rate was 25.40%–87.14%. With the increase of the concentration of adding liquid humic acid, the desorption capacity of adsorption state humic acid gradually increased, and the desorption rate gradually decreased. Compared to the three kinds of background electrolytes, Na2SO4 had the highest desorption rate of adsorptive humic acid in dairy manure biochar, and the range of desorption capacity was 0.15–0.78 mg/g. the concentration of liquid humic acid was 140 mg/L, the desorption capacity of the three kinds of background electrolytes to the adsorptive humic acid of dairy manure biochar have reached the maximum value, the order of desorption capacity was Na2SO4 >Na3PO4>NaCl. Na3PO4 had the greatest effect in the desorption rate of humic acid, the range of desorption rate was 17.24%–90.55%, NaCl had the minimal effect in the desorption rate of humic acid, the range of desorption rate was 8.22%–53.54%. The isothermal adsorption curves and isothermal desorption curves of the three kinds of background electrolytes in humic acid were fitted with Langmuir, and the correlation coefficients were significant. The results showed that the effects of different background electrolytes to dairy manure biochar on the adsorption and desorption of humic acid were studied, which provided a theoretical reference for soil fertility and soil fertility.

    参考文献
    相似文献
    引证文献
引用本文

黄惠群,曾和平,张健瑜,李 灿.不同电解质对牛粪生物质炭中腐殖酸吸附–解吸的影响[J].土壤,2019,51(1):100-106. HUANG Huiqun, ZENG Heping, ZhANG Jianyu, LI Can. Effects of Different Electrolytes on Adsorption-desorption Characteristics of Humic Acid in Dairy Manure Biochar[J]. Soils,2019,51(1):100-106

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2017-07-21
  • 最后修改日期:2017-09-19
  • 录用日期:2017-09-30
  • 在线发布日期: 2019-02-21
  • 出版日期: 2019-02-25