杭州湾典型潮滩湿地植物带沉积物磷吸附特征
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国家自然科学基金项目?(31000296)、“十二五”国家科技支撑计划专题项目?(2012BAC13B02-2)和国家林业公益性行业科研专项(201404210)资助


Adsorption Characteristics of Phosphate on Sediment Under Typical Vegetation Types in Hangzhou Bay
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    摘要:

    利用磷酸盐吸附动力学和等温吸附实验,研究了杭州湾潮滩湿地沉积物磷素吸附特征,并分析了不同植被类型及其沉积物理化性质对磷吸附的影响。结果表明,不同沉积物磷的吸附与释放过程均包括快速吸附 (0 ~ 1 h)、慢速吸附 (1 ~ 16 h) 和平衡 (16 ~ 72 h) 3 个阶段,不同植物没有明显影响这一趋势。改进的 Langmuir 模型拟合表明,沉积物最大吸附容量 (Qmax) 在 154.5 ~ 436.2 mg/kg 间, 生长植物的沉积物Qmax 明显高于光滩沉积物。沉积物自带可解吸磷 (NAP) 较少,在 1.853 ~ 4.777 mg/kg 间,NAP 在不同类型沉积物的分布趋势与 Qmax 值相似。4 种植被类型沉积物 EPC0 值低于潮汐水体中磷酸盐浓度,扮演着“汇”的角色,EPC0 在不同沉积物间差异较小。相关性分析显示,杭州湾潮滩沉积物 Qmax 和 NAP 受有机质、颗粒组成和总无机磷含量影响,其中 Qmax 还受电导率影响,而研究区 EPC0 与沉积物理化性质不存在显著相关性。植物可以通过影响沉积物的物理化学参数,从而影响磷的吸附过程。

    Abstract:

    Phosphate adsorption kinetics and isotherms on sediments under different vegetation types in Hangzhou Bay wetland were studied, and the influences of the sediment physicochemical properties on phosphorus sorption characteristics were analyzed. The results showed that there are three stages during sediment adsorption process with rapid adsorption (0–1 h), slow adsorption (1–16 h) and balance (16–72 h). The trend was not affected significantly by different plants. Indexes fitted from improved Langmuir model showed that sediment Qmax was between 154.5–436.2 mg/kg, and was significantly higher in sediment with plant growth than that of bare mudflat. Sediment NAP was between 1.853–4.777 mg/kg, indicating a low native adsorbed exchangeable phosphorus. NAP trends between different types of sediments were similar to that of Qmax values. Sediments EPC0 under different vegetation types were lower than soluble reactive phosphorus concentration in the overlying water. So the sediment acts as the “sink” of phosphorus from tidal water. The variation of EPC0 between different sediments was minor. Correlation analysis showed that the sediment Qmax and NAP in Hangzhou Bay wetland were affected by organic matter, particle composition and total inorganic phosphorus concentration, and Qmax was also affected by the electrical conductivity value. However, there are no significant correlations between sediments EPC0 and physicochemical properties. In conclusion of that, plants can affect the physical and chemical parameters of sediments, thus can affect the adsorption kinetics and isotherms of phosphorus.

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邵学新,梁 威,王 蒙,吴 明,叶小齐,蒋科毅.杭州湾典型潮滩湿地植物带沉积物磷吸附特征[J].土壤,2014,46(6):1032-1038. SHAO Xue-xin, LIANG Wei, WANG Meng, WU Ming, YE Xiao-qi, JIANG Ke-yi. Adsorption Characteristics of Phosphate on Sediment Under Typical Vegetation Types in Hangzhou Bay[J]. Soils,2014,46(6):1032-1038

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  • 在线发布日期: 2015-01-20
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